报告题目(中文)：金属¾有机框架涂覆的纳米粒子：一种控制异相催化的新途径
报告题目(英文)：Metal-Organic Framework Coated Nanoparticles: A New Way to Control Heterogeneous Catalysis
报告人姓名：Chia-Kuang Tsung（Boston College助理教授）
报告时间：2014-10-20, 15:00
报告地点：校本部东区环化楼915室
主办：纳米化学与生物学研究所
报告人简介(中文)：Chia-Kuang Tsung 2002-2007年在加州大学圣芭芭拉分校攻读博士学位，师从Galen D. Stucky教授，从事金属及金属氧化物的介观及纳米结构的制备及形貌控制的研究；2007-2010年在加州大学伯克利分校进行博士后研究工作，师从Gabor A. Somorjai与Peidong Yang教授，从事金属与金属氧化物纳米异相与光催化研究；2010年加入波士顿学院担任助理教授。Tsung教授目前共发表论文49篇，包括JACS, ACS Nano, Nature Chemistry等，引用近3000次，h-index 31。
报告内容简介：Heterogeneous catalysis is critical for the prosperity of human civilization. It provides access to the range of chemicals, materials, and fuels we use. Understanding and controlling catalytic processes are essential for developing improved energy storage and conversion technologies. Towards the long-term vision of precisely controlling active sites, our group has developed methods to coat nanoparticle catalysts with crystalline nanoporous materials, metal-organic-framework (MOF) and inorganic zeolite-based shells. The precise molecularly-defined pores intrinsic to the MOFs and zeolites provide a new mechanism to control the interaction between reactants undergoing catalytic transformations on the surface of the nanoparticles. We combine composition and facet controlled nanoparticles with precisely tuned pore structures to manipulate the diffusion, sorption, orientation, and conformation of the reactant molecules during the reaction. Our initial catalysis data demonstrate the new core-shell catalysts exhibit molecule-size-selective reactivity.
发表重要论文：
Kuo, C. H.; Tang, Y.; Chou, L. Y.; Sneed, B. T.; Brodsky, C. N.; Zhao, Z. P.; Tsung, C.-K., Yolk-Shell Nanocrystal@ZIF-8 Nanostructures for Gas-Phase Heterogeneous Catalysis with Selectivity Control. J. Am. Chem. Soc. 2012, 134 (35), 14345-14348.
Zhuang, J.; Kuo, C. H.; Chou, L. Y.; Liu, D. Y.; Weerapana, E.; Tsung, C.-K. Optimized Metal-Organic-Framework Nanospheres for Drug Delivery: Evaluation of Small-Molecule Encapsulation. Acs Nano. 2014, 8, 2812-2819.
Hu, P.; Zhuang, J.; Chou, L.-Y.; Lee, H. K.; Ling, X. Y.; Chuang, Y.-C.; Tsung, C.-K. Surfactant-Directed Atomic to Mesoscale Alignment: Metal Nanocrystals Encased Individually in Single-Crystalline Porous Nanostructures. J. Am. Chem. Soc. 2014
